Metal carboxylates in historical lacquer coatings (MeCaLaC). 01/11/2026 - 31/10/2030

Abstract

Following Europe's fascination for Asian lacquers, craftsmen attempted to reproduce the unique appearance and characteristics of these lacquers using local skills and raw materials. While Asian lacquers have been widely studied, their European counterparts remain poorly understood. This raises questions regarding their composition and reactivity, leading to a lack of understanding of their degradation and hindering proper conservation. This project addresses this gap by investigating the formation mechanisms of metal carboxylates (soaps and oxalates), commonly found in degraded lacquer areas, to clarify the link between their formation and macroscopic degradation patterns. The research will proceed in three stages: 1)identifying original lacquer ingredients through historical sources and chemical characterization of historical objects, 2)shedding light on the abundance, speciation and distribution of metal carboxylates in lacquer using synchrotron-based techniques and 3)correlating materials, environmental conditions and degradation phenomena by studying artificially aged mock-up samples. Unravelling these mechanisms is essential to assess which internal (materials, stratigraphy) and external (environmental conditions, dust) factors can promote the formation of metal carboxylates and how they affect lacquer stability. The results will help to explain the currently observed degradation patterns, identify objects at risk and enable to provide guidelines for their conservation.

Researcher(s)

Research team(s)

Funding

  • FWO

Project type(s)

  • Research Project

Imcotech – Impermeable coating techniques for historical horse-drawn vehicles. 01/08/2024 - 31/07/2028

Abstract

Up to the early 20th century, carriages and sleighs have played a central role in society and thus are present in many museum collections today. Yet, the heritage of horse-drawn vehicles (Hippomobile heritage) remains a vastly understudied area in heritage scholarship. A first effort to shed light on this unique heritage has been made, since October 2022, with the Belcaire project, aiming at developing an informed conservation plan for the hippomobile heritage collection of the Royal Museums of Art and History (KMKG-MRAH) in Brussels. However, given the material complexity of these vehicles, focused analytical-technical research projects are also necessary to fully understand the chemistry of the different materials constituting a carriage. This is where the Imcotech project comes into play, aiming at gaining a deeper understanding of one of the most complex materials found in carriages: lacquer coatings. Because of their nature and use, horse-drawn vehicles were systematically exposed to environmental agents such as (UV) light, moisture, atmospheric pollution gases and dirt/dust. The water-sensitive materials that form part of these vehicles were protected against the adverse effect of the environment through the application of impermeable lacquer coatings. These coatings had also a fundamental decorative function, since they would ultimately determine the final appearance of the vehicles (conceived not only as a mean of transport, but also as a fashion statement and a symbol of social status). Today, the complete lack of research on the history, composition and chemistry of these complex multilayered coatings, makes it impossible to design a well-informed conservation plan for hippomobile heritage. Consequently, the lacquer on the exterior of historical horse-drawn vehicles, when original, is often found in a poor conservation state. Given the key twofold function of lacquer on carriages and sleighs, i.e., protective and decorative, its degradation can have dramatic consequences on the overall condition of the objects and cause a drastic loss of aesthetic, historical and thus (future) valorization value for the museums they are kept in. Imcotech aims at filling this critical knowledge gap by means of a multidisciplinary approach, combining (1) research of written and visual sources and (2) reproduction of historical lacquer recipes, with (3) material characterization of historical vehicles by means of advanced analytical methods. The fundamental information obtained in this project will allow to shed light on the composition and technology of these impermeable coatings. These results will complement previous research conducted on European lacquer for indoor applications (ELinC project, focus on furniture and other small objects), finally allowing to obtain a complete picture on lacquer materials and on the historical evolution of waterproofing and material technology as a whole. Moreover, the results of Imcotech will represent a key step towards completion of the ambitious goal of Belcaire, ultimately enabling a better preservation of hippomobile heritage for future generations.

Researcher(s)

Research team(s)

Funding

  • BOF

Project type(s)

  • Research Project